A　scheme　is　proposed　to　generate　the　W　state　and　NOON　state　for　the　collective　molecular　modes　of　distant　polar　molecules　ensembles　via　a　triple　hybrid　device.　Through　the　virtual　excitation　of　the　microwave　photons　of　the　transmission-line　resonators,　the　interaction　between　the　superconducting　charge　qubit　and　the　polar　molecules　induces　the　entanglement　for　the　collective　modes　of　the　polar　molecules.　The　enhanced　effective　coupling　strength　between　the　superconducting　charge　qubit　and　the　polar　molecules　enables　to　generate　the　W　state　and　NOON　state　with　high　fidelity.　©　2013　Elsevier　B.V.　All　rights　reserved.