Designed synthesis of size-tunable Ag2S nanoclusters via distinguishable C-S bond cleavage reaction of alkyl- and aryl-thiolates - Details

author：

Chen, Hang-Qing (Chen, Hang-Qing.) ^[1] | He, Xin (He, Xin.) ^[2] | Guo, Hui (Guo, Hui.) ^[3] | Fu, Nan-Yan (Fu, Nan-Yan.) ^[4] | Zhao, Liang (Zhao, Liang.) ^[5]

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Abstract：

We　report　herein　the　synthesis　of　two　different　silver　clusters　of　aryl-　and　alkyl-thiolates.　These　two　cluster　complexes　exhibited　biased　C-S　bond　cleavage　reaction　rates　upon　removing　protective　hexamethylazacalix[6]pyridine　(Py[6])　ligands,　which　was　applied　in　the　fabrication　of　silver　sulfide　nanoclusters　with　variable　and　controllable　sizes.　©　The　Royal　Society　of　Chemistry　2015.

Keyword：

Chemical bonds Nanoclusters Reaction rates Silver compounds Sulfur compounds

Community：

[ 1 ] [Chen, Hang-Qing]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing; 100084, China
[ 2 ] [Chen, Hang-Qing]Department of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 3 ] [He, Xin]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing; 100084, China
[ 4 ] [Guo, Hui]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing; 100084, China
[ 5 ] [Fu, Nan-Yan]Department of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 6 ] [Zhao, Liang]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing; 100084, China

Reprint 's Address：

[zhao, liang]key laboratory of bioorganic phosphorus chemistry and chemical biology (ministry of education), department of chemistry, tsinghua university, beijing; 100084, china

Email：

zhaolchem@mail.tsinghua.edu.cn

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Source ：

Dalton Transactions

ISSN： 1477-9226

Year： 2015

Issue： 9

Volume： 44

Page： 3963-3966

4 . 1 7 7

JCR@2015

3 . 5 0 0

JCR@2023

ESI HC Threshold：265

JCR Journal Grade：1

CAS Journal Grade：2

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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