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author:

Li, Huiquan (Li, Huiquan.) [1] | Liu, Yuxing (Liu, Yuxing.) [2] | Cui, Yumin (Cui, Yumin.) [3] | Zhang, Wenbao (Zhang, Wenbao.) [4] | Fu, Cong (Fu, Cong.) [5] | Wang, Xinchen (Wang, Xinchen.) [6]

Indexed by:

EI

Abstract:

DyVO4/iodine modified graphitic carbon nitride (DyVO4/g-C3N4I) composite semiconductors with different weight percents of DyVO4 were successfully synthesized by a facile heating method, and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), UV-vis diffuse reflection spectroscopy (UV-vis DRS), photoluminescence (PL) and electron paramagnetic resonance (EPR) spectra, N2 adsorption-desorption analysis and photo-electrochemical measurement. The resulting DyVO4/g-C3N4I semiconductor with a suitable weight percents of 6.3% DyVO4 showed the highest visible-light photoactivity, and its degradation ratio for methylene blue was more than 1.8 time higher than that of DyVO4, g-C3N4 and g-C3N4I. The H2 evolution rate of 6.3% DyVO4/g-C3N4I was 10.6, 4.7 and 1.7 times higher than that of DyVO4, g-C3N4 and g-C3N4I, respectively, while still having excellent reusability and stability. The obviously enhanced photoactivity of 6.3% DyVO4/g-C3N4I is mainly ascribed to the fact that the proper DyVO4 modified g-C3N4I increase its specific surface area, decrease band-gap energy, enhance absorption in the 400-700nm region and promote efficient separation of photo-generated carriers. The mechanism on the improvement of visible-light photoactivity is discussed. © 2015 Elsevier B.V.

Keyword:

Aromatic compounds Carbon nitride Conjugated polymers Dysprosium compounds Electron spin resonance spectroscopy Energy gap High resolution transmission electron microscopy Image enhancement Light Paramagnetic resonance Photoelectron spectroscopy Reusability X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Li, Huiquan]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350002, China
  • [ 2 ] [Li, Huiquan]School of Chemistry and Materials Engineering, Fuyang Normal College, Fuyang; 236037, China
  • [ 3 ] [Liu, Yuxing]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350002, China
  • [ 4 ] [Cui, Yumin]School of Chemistry and Materials Engineering, Fuyang Normal College, Fuyang; 236037, China
  • [ 5 ] [Zhang, Wenbao]School of Chemistry and Materials Engineering, Fuyang Normal College, Fuyang; 236037, China
  • [ 6 ] [Fu, Cong]School of Chemistry and Materials Engineering, Fuyang Normal College, Fuyang; 236037, China
  • [ 7 ] [Wang, Xinchen]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350002, China

Reprint 's Address:

  • [wang, xinchen]state key laboratory of photocatalysis on energy and environment, college of chemistry, fuzhou university, fuzhou; 350002, china

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2016

Volume: 183

Page: 426-432

9 . 4 4 6

JCR@2016

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:235

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 60

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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