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[期刊论文]

Supported ionic liquids as green catalyst for 2-butanol synthesis from transesterification of sec-butyl acetate

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author:

Yang, Jinbei (Yang, Jinbei.) [1] | Zeng, Ting (Zeng, Ting.) [2] | Cai, Dongren (Cai, Dongren.) [3] | Unfold

Indexed by:

EI

Abstract:

Two supported ionic liquids using molecular sieve SBA-15 as supporter were prepared and employed as efficient catalysts for the synthesis of 2-butanol (SBOH) via the transesterification of sec-butyl acetate and methanol (MeOH). [SBA-15-Ps-im]HSO4 performed better in the catalytic activity and was chosen for further studying the influence of experimental conditions. The effects of various parameters, such as the catalyst dosage, initial reactant molar ratio, and reaction time on the reaction were investigated systematically. The maximum conversion of sec-butyl acetate (89.2%) was obtained under the optimum reaction conditions. In addition, the catalyst of supported ionic liquids can be easily separated by simple filtration, and the reusability test indicates that the catalyst has outstanding utility for repeated use. © 2016 Curtin University of Technology and John Wiley & Sons, Ltd. © 2016 Curtin University of Technology and John Wiley & Sons, Ltd.

Keyword:

Catalyst activity Catalyst supports Filtration Ionic liquids Molar ratio Molecular sieves Reusability Transesterification

Community:

  • [ 1 ] [Yang, Jinbei]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 2 ] [Yang, Jinbei]School of Ocean Science and Biochemistry Engineering, Fuqing Branch of Fujian Normal University, Fuzhou; Fujian; 350300, China
  • [ 3 ] [Zeng, Ting]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 4 ] [Cai, Dongren]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 5 ] [Li, Ling]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 6 ] [Tang, Wenli]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 7 ] [Hong, Ruoyu]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 8 ] [Qiu, Ting]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China

Reprint 's Address:

  • [qiu, ting]school of chemical engineering, fuzhou university, fuzhou; fujian; 350108, china

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Source :

Asia-Pacific Journal of Chemical Engineering

ISSN: 1932-2135

Year: 2016

Issue: 6

Volume: 11

Page: 901-909

0 . 8 3 6

JCR@2016

1 . 4 0 0

JCR@2023

ESI HC Threshold:235

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

30 Days PV: 0

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