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author:

Cai, Dongren (Cai, Dongren.) [1] | Yang, Jinbei (Yang, Jinbei.) [2] | Da, Hairong (Da, Hairong.) [3] | Li, Ling (Li, Ling.) [4] | Wang, Hongxing (Wang, Hongxing.) [5] | Qiu, Ting (Qiu, Ting.) [6]

Indexed by:

EI

Abstract:

Densities, ρ and viscosities, η of N,N-dimethyl-N-(3-sulfopropyl)cyclohexylammo-nium tosylate ([CyN1,1PrSO3H][Tos]) with water and methanol were measured, at temperatures from 303.15 K to 328.15 K with 5 K interval and 0.1013 MPa, as a function of [CyN1,1PrSO3H][Tos] molality (or mass fraction). The isobaric thermal expansion coefficient, molecular volume, standard molar entropy, and lattice energy of the pure IL were obtained based on the density data of pure IL. The apparent molar volume, Vφ, infinite dilution apparent molar expansibility, Eφ∞ and energy barrier, E were calculated from the experimental data. The Redlich-Mayer equation was used to evaluate infinite dilution apparent molar volume, Vφ∞. In addition, viscosities can be described satisfactorily by Vogel-Fulcher-Tammann (VFT) equation. The Vφ∞ values of the IL in water are higher than those in methanol, which suggests that the ion-solvent interactions for [CyN1,1PrSO3H][Tos] + water binary system are stronger than those for [CyN1,1PrSO3H][Tos] + methanol. And the energy barrier values decrease with the drop of IL mass fraction in both systems, indicating that the viscosity changes of binary mixtures are more sensitive to the temperature at high composition of the IL. © 2016

Keyword:

Binary mixtures Density (specific gravity) Energy barriers Ionic liquids Methanol Organic solvents Sulfur compounds Thermal expansion Viscosity Volume measurement

Community:

  • [ 1 ] [Cai, Dongren]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 2 ] [Yang, Jinbei]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 3 ] [Yang, Jinbei]School of Ocean Science and Biochemistry Engineering, Fuqing Branch of Fujian Normal University, Fuzhou; Fujian; 350300, China
  • [ 4 ] [Da, Hairong]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 5 ] [Li, Ling]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 6 ] [Wang, Hongxing]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 7 ] [Qiu, Ting]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China

Reprint 's Address:

  • [li, ling]school of chemical engineering, fuzhou university, fuzhou; fujian; 350116, china

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Source :

Journal of Molecular Liquids

ISSN: 0167-7322

Year: 2017

Volume: 229

Page: 389-395

4 . 5 1 3

JCR@2017

5 . 3 0 0

JCR@2023

ESI HC Threshold:226

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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