This　paper　would　first　present　the　distribution　of　minor　and　trace　elements　in　the　Cu-Fe-S　minerals　in　the　deposits　of　Zijinshan　orefield　by　using　EPMA　and　LA-ICP-MS　micro-analysis.　The　results　show　copper　minerals　from　the　upper　Zijinshan　open-pit　have　the　distinct　high　Se　contents,　of　which　covellite　develops　the　good　shape　of　selenium　zoning　with　the　highest　Se　of　1.57%.　LA-ICP-MS　micro-analysis　showed　that　the　digenite　and　djurleite　contain　significant　concentration　of　Au　(＞1×10-6)　and　Ag,　and　are　the　major　gold-carrier,　in　which　also　have　different　trace　element　signatures　with　significant　concentration　of　Bi,　Se,　and　Sn　compared　to　the　secondary　digenite.　Bornite　is　the　major　carriers　of　silver　and　bismuth　in　Zijinshan　orefield,　and　contanins　alternative　concentration　of　Bi　and　Ag　in　different　mineralized　stage.　Bornite　contains　higher　Bi　and　less　Ag　and　Sn　in　the　high　sulfidation　stage　when　compared　to　the　low-middle　sulfidation　stage.　Chalcopyrite　contains　less　Ag　but　highest　In　contents　(~30×10-6),　is　the　major　indium-carrier.　Besides,　ore　minerals　in　Zijinshan　orefield　all　contain　significant　concentration　of　Se,　Te,　Ge　and　As,　which　implies　that　the　mineralization　in　Zijinshan　district　was　intimately　related　to　the　volcanism.　The　occurrence　of　anomalous　zone　of　W,　Sn,　Mo,　Bi　and　In　in　Zijinshan　orefield　is　a　potential　geochemical　indicator　of　transition　between　porphyry　and　high　sulfidation　mineralization,　which　indicates　a　porphyry　mineralization　in　the　depth　of　Zijinshan.　©　2017,　Editorial　Office　of　Earth　Science　Frontiers.　All　right　reserved.