An　efficient　and　highly　practical　palladium-catalyzed　arylperfluoroalkylation　of　unactivated　olefins　is　presented　here.　A　variety　of　perfluoroalkylated　heterocyclic　derivatives　can　be　obtained　in　high　regioselectivity.　The　reaction　proceeds　mildly　without　the　electronic　activation　of　the　aryl　group　and　features　high　generality,　low-cost　fluoroalkylated　sources　and　good　functional-group　compatibility.　©　2017　American　Chemical　Society.