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author:

Jia, Mingmin (Jia, Mingmin.) [1] | Feng, Yi (Feng, Yi.) [2] | Qiu, Jianhao (Qiu, Jianhao.) [3] | Lin, Xiaocheng (Lin, Xiaocheng.) [4] | Yao, Jianfeng (Yao, Jianfeng.) [5]

Indexed by:

EI

Abstract:

UiO-66-NH2 nanocrystals were synthesized and embedded into bromomethylated poly(phenylene oxide)/polyethersulfone (BPPO/PES) polymer matrix to form UiO-66-NH2/BPPO/PES mixed matrix membranes (MMMs). The crystalline structure, interaction between UiO-66-NH2 and BPPO, and dispersion of UiO-66-NH2 were characterized by FTIR, XRD, and SEM. Nanoparticle dispersion was drastically enhanced with the assistance of BPPO, giving an improved adhesion between the polymer and filler particles. Owing to the intrinsic adsorption property of UiO-66-NH2 and BPPO to CO2, the CO2 permeability was significantly increased. As a result, the UiO-66-NH2/BPPO/PES membrane exhibited enhanced gas separation performance, where CO2/N2 and H2/N2 ideal selectivities were increased to 50.2 and 302.4 with a CO2 permeability of 125.6 Barrer. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46759. © 2018 Wiley Periodicals, Inc.

Keyword:

Aromatic compounds Carbon dioxide Dispersions Filled polymers Gas permeable membranes Polyphenylene oxides Separation

Community:

  • [ 1 ] [Jia, Mingmin]College of Chemical Engineering, Jiangsu Key Lab for the Chemistry & Utilization of Agricultural and Forest Biomass, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing; 210037, China
  • [ 2 ] [Feng, Yi]College of Chemical Engineering, Jiangsu Key Lab for the Chemistry & Utilization of Agricultural and Forest Biomass, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing; 210037, China
  • [ 3 ] [Qiu, Jianhao]College of Chemical Engineering, Jiangsu Key Lab for the Chemistry & Utilization of Agricultural and Forest Biomass, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing; 210037, China
  • [ 4 ] [Lin, Xiaocheng]Laboratory of Chemical Process Intensification, College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 5 ] [Yao, Jianfeng]College of Chemical Engineering, Jiangsu Key Lab for the Chemistry & Utilization of Agricultural and Forest Biomass, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing; 210037, China

Reprint 's Address:

  • [yao, jianfeng]college of chemical engineering, jiangsu key lab for the chemistry & utilization of agricultural and forest biomass, jiangsu key lab of biomass-based green fuels and chemicals, nanjing forestry university, nanjing; 210037, china

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Source :

Journal of Applied Polymer Science

ISSN: 0021-8995

Year: 2018

Issue: 46

Volume: 135

2 . 1 8 8

JCR@2018

2 . 7 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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