Designed synthesis of a proton-conductive Ho-MOF with reversible dehydration and hydration - Details

author：

Wang, Sa-Sa (Wang, Sa-Sa.) ^[1] | Wu, Xiao-Yuan (Wu, Xiao-Yuan.) ^[2] | Li, Zhong (Li, Zhong.) ^[3] | Lu, Can-Zhong (Lu, Can-Zhong.) ^[4]

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Abstract：

A　Ho-MOF　([Ho(SIP)(H2O)5]·3H2O　(1),　NaH2SIP　=　monosodium　5-sulfoisophthalic　acid)　was　designed　and　synthesized　for　proton　conductivity.　It　showed　a　proton　conductivity　of　8.2　×　10-4　S　cm-1　at　343　K　and　98%　relative　humidity.　Besides,　compound　1　showed　excellent　water　and　chemical　stability　as　well　as　reversible　dehydration　and　hydration　closely　related　to　the　proton　conductivity.　©　2019　The　Royal　Society　of　Chemistry.

Keyword：

Chemical stability Dehydration Hydration Proton conductivity Sodium compounds

Community：

[ 1 ] [Wang, Sa-Sa]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
[ 2 ] [Wu, Xiao-Yuan]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China
[ 3 ] [Li, Zhong]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou Fujian; 350108, China
[ 4 ] [Lu, Can-Zhong]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou Fujian; 350002, China

Reprint 's Address：

[lu, can-zhong]cas key laboratory of design and assembly of functional nanostructures, fujian key laboratory of nanomaterials, fujian institute of research on the structure of matter, chinese academy of sciences, fuzhou fujian; 350002, china

Email：

czlu@fjirsm.ac.cn

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Source ：

Dalton Transactions

ISSN： 1477-9226

Year： 2019

Issue： 27

Volume： 48

Page： 9930-9934

4 . 1 7 4

JCR@2019

3 . 5 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 9

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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