Perfluorocarboxylic Anhydrides Triggered Cyclization: Access to 4-Perfluoroalkylpyridines - Details

author：

Wang, Zeng (Wang, Zeng.) ^[1] | You, Chenhui (You, Chenhui.) ^[2] | Wang, Changfang (Wang, Changfang.) ^[3] | Weng, Zhiqiang (Weng, Zhiqiang.) ^[4]

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Abstract：

A　double　nucleophilic　addition-cyclization-elimination　cascade　is　developed,　that　allows　various　2,6-diaryl-4-perfluoroalkylpyridines　to　be　synthesized　in　one　step　from　easily　available　enamides　and　perfluorocarboxylic　anhydrides.　The　procedure　is　also　operationally　simple　and　scalable　and　provides　access　to　the　facial　construction　of　4-fluoroalkylpyridines,　which　are　of　great　interest　in　medicinal　chemistry.　Copyright　©　2019　American　Chemical　Society.

Keyword：

Addition reactions Cyclization

Community：

[ 1 ] [Wang, Zeng]State Key Lab. of Photocatalysis on Ener. and Environ. and Key Lab. of Molecule Synthesis and Funct. Discov., College of Chemistry, Fuzhou University, Fujian; 350108, China
[ 2 ] [You, Chenhui]State Key Lab. of Photocatalysis on Ener. and Environ. and Key Lab. of Molecule Synthesis and Funct. Discov., College of Chemistry, Fuzhou University, Fujian; 350108, China
[ 3 ] [Wang, Changfang]Institute of Plant Protection, Fujian Academy of Agricultural Sciences, Fuzhou; 350013, China
[ 4 ] [Weng, Zhiqiang]State Key Lab. of Photocatalysis on Ener. and Environ. and Key Lab. of Molecule Synthesis and Funct. Discov., College of Chemistry, Fuzhou University, Fujian; 350108, China

Reprint 's Address：

[wang, changfang]institute of plant protection, fujian academy of agricultural sciences, fuzhou; 350013, china

Email：

295075872@qq.com

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2019

Issue： 22

Volume： 84

Page： 14926-14935

4 . 3 3 5

JCR@2019

3 . 4 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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