Mg3Pt(BO3)2O2: The first platinum borate from the flux technique - Details

author：

Indexed by：

Abstract：

Investigation　of　the　Pt-B-O　system　reveals　the　first　magnesium　platinum　borate　Mg3Pt(BO3)2O2　obtained　from　the　high　temperature　flux　method.　The　compound　crystallizes　in　the　centrosymmetric　monoclinic　space　group　C2/m　(no.　12)　with　the　lattice　parameters　of　a　=　16.8073(8)　Å,　b　=　3.10610(1)　Å,　c　=　5.2107(2)　Å,　and　β　=　90.546(4)°　(Z　=　2).　The　crystal　structure　of　Mg3Pt(BO3)2O2　is　based　upon　isolated　BO3　triangles　and　PtO6　and　MgO6　octahedra.　The　PtO6　octahedra　are　connected　with　each　other　in　an　edge-sharing　manner　forming　one　dimensional　(1D)　chains.　Each　of　the　PtO6　octahedra　links　with　two　BO3　units　to　form　anionic　[Pt(BO3)2O2]6-　chains　along　the　b-axis.　MgO6　octahedra　are　arranged　in　the　form　of　two　dimensional　(2D)　layers.　The　2D　MgO6　layers　are　further　connected　by　the　anionic　[Pt(BO3)2O2]6-　chains　into　the　3D　framework　structure　of　Mg3Pt(BO3)2O2.　The　material　was　experimentally　and　theoretically　characterized　in　regards　to　its　optical　and　spectroscopic　properties.　©　2019

Keyword：

Calculations Crystal structure Magnesium compounds Optical properties Platinum Platinum compounds Single crystals

Community：

[ 1 ] [Hao, Yucheng]Department of Chemical and Material Engineering, Hefei University, Hefei; 230000, China
[ 2 ] [He, Linbo]Department of Chemical and Material Engineering, Hefei University, Hefei; 230000, China
[ 3 ] [Ge, Guangjie]Department of Chemical and Material Engineering, Hefei University, Hefei; 230000, China
[ 4 ] [Zhang, Quanzheng]Department of Chemical and Material Engineering, Hefei University, Hefei; 230000, China
[ 5 ] [Luo, Ningjing]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 6 ] [Huang, Shuping]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 7 ] [Huang, Shuping]Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, Xiamen; Fujian; 361005, China
[ 8 ] [Li, Haijian]National Key Lab of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an; 710065, China
[ 9 ] [Alekseev, Evgeny V.]Institute of Energy and Climate Research (IEK-6), Forschungszentrum Jülich GmbH, Jülich; 52428, Germany
[ 10 ] [Alekseev, Evgeny V.]Institiut Für Kristallographie, RWTH Aachen University, Aachen; 52066, Germany

Reprint 's Address：

[hao, yucheng]department of chemical and material engineering, hefei university, hefei; 230000, china

Email：

haoyco@hfuu.edu.cn

Show more details

Related Keywords：

Itinerant metamagnetic transition in the ferromagnet LuC o3 induced by high field: Instability of the 3d-electron subsystem
2020，Physical Review B
Explore the possibility of forming fcc high entropy alloys in equal-atomic systems CoFeMnNiM and CoFeMnNiSmM
2011，Journal of Shanghai Jiaotong University (Science)
First-principles calculations of steady-state voltage-controlled magnetism: Application to X-ray absorption spectroscopy experiments
2020，Physical Review Research
Experimental Observations versus First-Principles Calculations for Ni–Mn–Ga Ferromagnetic Shape Memory Alloys: A Review
2022，Physica Status Solidi - Rapid Research Letters
Transport properties of doped permalloy via ab initio calculations: Effect of host disorder
2020，Physical Review B

Source ：

Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2020

Volume： 281

3 . 4 9 8

JCR@2020

3 . 2 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search Engineering Village

Type
Departments

All Years Choose Year From to