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author:

Wang, Xianying (Wang, Xianying.) [1] | Wang, Yingshu (Wang, Yingshu.) [2] | Gao, Meichao (Gao, Meichao.) [3] | Shen, Jinni (Shen, Jinni.) [4] | Pu, Xipeng (Pu, Xipeng.) [5] | Zhang, Zizhong (Zhang, Zizhong.) [6] | Lin, Huaxiang (Lin, Huaxiang.) [7] | Wang, Xuxu (Wang, Xuxu.) [8]

Indexed by:

EI

Abstract:

Construction of composite semiconductors is an effective solution to elevate the efficiency of photocatalysis by prolonging lifetime of photogenerated hole and electrons. Herein, a heterojunction structure composite BiVO4/Bi4Ti3O12 was synthesized via a facile in situ hydrothermal condition. The novel composite photocatalyst has excellent photocatalytic ability to reduce CO2 with H2O into CH3OH and CO. The BiVO4/10 % Bi4Ti3O12 sample shows the highest yields of CH3OH and CO up to 16.6 and 13.29 μmol g−1 h−1, which was 12.39 and 5.68 times higher than that of pure BiVO4, and 9.88 and 2.80 times higher than that of pure Bi4Ti3O12, respectively. Such a high activity is attributed to the type II heterojunction structure which significantly enhances separation of photogenerated carriers and promotes collaboration between the water oxidation on the Bi4Ti3O12 and the CO2 reduction on BiVO4. The photocatalytic reaction mechanism of CO2 on the composite was proposed according to experiment results. © 2020 Elsevier B.V.

Keyword:

Bismuth compounds Carbon dioxide Heterojunctions Photocatalysis Titanium compounds

Community:

  • [ 1 ] [Wang, Xianying]College of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 2 ] [Wang, Yingshu]College of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 3 ] [Gao, Meichao]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 4 ] [Gao, Meichao]School of Materials Science and Engineering, Liaocheng University, Liaocheng; Shandong, China
  • [ 5 ] [Shen, Jinni]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 6 ] [Pu, Xipeng]School of Materials Science and Engineering, Liaocheng University, Liaocheng; Shandong, China
  • [ 7 ] [Zhang, Zizhong]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 8 ] [Lin, Huaxiang]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China
  • [ 9 ] [Wang, Xuxu]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, China

Reprint 's Address:

  • [wang, yingshu]college of chemical engineering, fuzhou university, fuzhou, china

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2020

Volume: 270

1 9 . 5 0 3

JCR@2020

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 201

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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