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author:

Huang Liang-Liang (Huang Liang-Liang.) [1] | Huang Yan (Huang Yan.) [2] | Chen Yan-Kai (Chen Yan-Kai.) [3] | Ding Yun-Hua (Ding Yun-Hua.) [4] | Zhang Wei-Feng (Zhang Wei-Feng.) [5] | Li Xiao-Jing (Li Xiao-Jing.) [6] | Wu Xiao-Ping (Wu Xiao-Ping.) [7]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

A simple and green method for the determination of trace bisphenol A (BPA) was established by coupling supported ionic liquid solid-phase extraction to beta-cyclodextrin modified ionic liquids carbon paste electrode-based electrochemical detection (SILs-SPE-ED). The synthesized imidazolium ionic liquids modified styrene type macroporous resin was used as adsorbent for SPE of BPA. The experimental parameters that affected the extraction efficiency were investigated and optimized. Dynamic adsorption test showed that the maximum adsorption capacity of BPA on the SILs-SPE cartridge was 10.1 mg g(-1), and the enrichment factor was 40. The calibration curve showed a good linearity between the anodic current and the BPA concentration in the range of 1.0 x 10(-8)-1.0 x 10(-6) M. The detection limit was 4.16 nM (equal to 0.95 mu g L-1). The SILs-SPE-ED method, with the advantages including high sensitivity and good practicability, was applied to the analysis of real water and plastic samples, and the results agreed well with HPLC method.

Keyword:

Bisphenol A Electrochemical detection Ionic liquid-based carbon paste electrode Solid phase extraction Supported ionic liquids

Community:

  • [ 1 ] [Huang Liang-Liang]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China
  • [ 2 ] [Huang Yan]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China
  • [ 3 ] [Chen Yan-Kai]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China
  • [ 4 ] [Ding Yun-Hua]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China
  • [ 5 ] [Zhang Wei-Feng]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China
  • [ 6 ] [Wu Xiao-Ping]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China
  • [ 7 ] [Chen Yan-Kai]Fujian Inspect & Res Inst Prod Qual, Fuzhou 350002, Peoples R China
  • [ 8 ] [Li Xiao-Jing]Tech Ctr Fujian Entry Exit Inspect & Quarantine B, Fuzhou 350001, Peoples R China

Reprint 's Address:

  • 吴晓苹

    [Wu Xiao-Ping]Fuzhou Univ, Coll Chem, Minist Educ, Key Lab Anal & Detect Food Safety, Fuzhou 350108, Peoples R China

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Source :

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY

ISSN: 0253-3820

CN: 22-1125/O6

Year: 2015

Issue: 3

Volume: 43

Page: 313-318

0 . 5 6 6

JCR@2015

1 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:265

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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