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Abstract:
The title compound has been synthesized by high-temperature solid state reaction. The crystal structure was determined by single crystal X-ray diffraction method. The crystal belongs to orthorhombic system with space group Pnma, Z=4, a=6.480(1), b=3.5839(6), c=16.994(4) angstrom, V=392.5(1) angstrom(3), D-c=9.37g.cm(-3), lambda(MoKa)=0.71069 angstrom, mu(MoKa)=514.43cm(-1) and F(000)=932. The final R is 0.051 for 706 observations. TaNi2Te2 is a new metal-rich layered ternary telluride. In the structure trigonal metal sheets are sandwiched below and above by Te layers, leading to planar trigonal coordination for Ta and trigonal pyramidic coordination for Ni by Te atoms. An important structural character of this compound is that all planar five-member TeNi4 rings are fused together to form an extended structure, and each Ta atom is sandwiched by two TeNi4 rings.
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ACTA PHYSICO-CHIMICA SINICA
ISSN: 1000-6818
CN: 11-1892/O6
Year: 1994
Issue: 6
Volume: 10
Page: 508-513
1 0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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