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author:

JIN, LP (JIN, LP.) [1] | WANG, MZ (WANG, MZ.) [2] | LIU, SX (LIU, SX.) [3] | HUANG, JL (HUANG, JL.) [4] | WANG, RF (WANG, RF.) [5] | CAI, GL (CAI, GL.) [6]

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Scopus SCIE

Abstract:

The title complex crystalizes in the space group P (1) over bar with a=1.3349(7), b=1.9790(4), c=1.2784 (7) nm, alpha=97.67(1), beta=10636(1), gamma=91.71(1)degrees, Z=2, M(r)=1475.19 and the final R=0.051. Each asymmetric species in the crystal contains two crystallographically different Eu(p-CH3C6H4COO)(3)(C12H8HN2) units. Two types of binuclear molecules are formed by the combination of each of the units through inversion with corresponding units of the closest asymmetric species. The former contains 4 bridged carboxylate groups bonded to the two central europium (III) ions, and the latter, only 2 bridged carboxylate anions. Their Eu-Eu atomic distances are 0.4203 and 0.5298 nm respectively. In the F-7(0) --> D-5(0) excitation spectrum of the complex, there are two sharp peaks at 580.07 and 580.73 nm. This shows that the complex has two Eu(III) sites. Two different sets of D-5(0) --> F-7(j)(j=1-4) luminescence spectra have been obtained at the selectively excited D-5(0) levels of the complex, which indicates that Eu(IlI) ions in the complex have unequally chemical environments. This is in agreement with the results of the structure determination.

Keyword:

CRYSTAL STRUCTURE EUROPIUM LUMINESCENCE SPECTRA TERNARY COMPLEX

Community:

  • [ 1 ] FUZHOU UNIV,DEPT CHEM,FUZHOU 350002,PEOPLES R CHINA
  • [ 2 ] HEBEI NORMAL UNIV,DEPT CHEM,SHIJIAZHUANG 050091,PEOPLES R CHINA

Reprint 's Address:

  • [JIN, LP]BEIJING NORMAL UNIV,DEPT CHEM,BEIJING 100875,PEOPLES R CHINA

Email:

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Source :

SCIENCE IN CHINA SERIES B-CHEMISTRY LIFE SCIENCES & EARTH SCIENCES

ISSN: 1001-652X

Year: 1995

Issue: 1

Volume: 38

Page: 1-9

0 . 4 7 9

JCR@1998

Cited Count:

WoS CC Cited Count: 40

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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