The　recent　progress　in　some　spectrum　methods　on　the　structures　of　metal　phthalocyanine　was　introduced.　IR　and　UV/Vis　spectral　properties　of　phthalocyanine　were　presented　systematically,　especially　the　effect　of　the　types,　numbers　and　positions　of　the　peripheral　substituted　groups　as　well　as　the　different　aggregation　states　in　solution　on　the　UV/Vis　spectra,the　characterization　method　of　the　isomers　of　tetra-substituted　metal-phthalocyanine　by　NMR　was　also　discussed.