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author:

Ma, Z (Ma, Z.) [1] | Lin, Y (Lin, Y.) [2] | Chen, ZN (Chen, ZN.) [3]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

Two silver(I) complexes were obtained by the reaction of a N-6 ligand with [Ag(PPh3)(2)(MeCN)](SbF6). In complex [AgL1(PPh3)](SbF6) 1, the silver center is bound to three N donors of the nitrogen ligand and P donor of one triphenylphosphine group, forming an irregular AgN3P tetrahedron. In complex [Ag(PPh3)(4)](SbF6) 2, the Ag+ ion is coordinated to four triphenylphosphine groups, affording a tetrahedral geometry. Crystal data for complex 1: C30H37AgF6N6PSb, M-r = 856.25, orthorhombic, space group Pbca, a = 19.0702(9), b = 15.9047(7), c = 21.498(1) Angstrom, V = 6520.5(6) Angstrom(3), Z = 8, D-c = 1.744 g/cm(3), F(000) = 3408, mu = 1.544 mm(-1), the final R = 0.0367 and wR 0.1077 for 5325 observed reflections with I > 2sigma(I); and those for 2: C72H60AgF6P4Sb, M-r = 1392.70, trigonal, space group R $(3) over bar $ a = 14.4577(6), b = 14.4577(6), c = 51.544(2) Angstrom, V = 9330.5(7) Angstrom(3), Z = 6, D-c = 1.487 g/cm(3), F(000) = 4224, mu = 0.913 mm(-1), the final R = 0.0352 and wR = 0.1089 for 3498 observed reflections with I > 2sigma(I).

Keyword:

coordination crystal structure N-6 ligand silver(I) complexes

Community:

  • [ 1 ] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] Fuzhou Univ, Cent Lab, Fujian 350002, Peoples R China

Reprint 's Address:

  • [Chen, ZN]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2004

Issue: 11

Volume: 23

Page: 1277-1281

0 . 7 3 4

JCR@2004

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Online/Total:11/10046835
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