• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

[期刊论文]

Hydrothermal synthesis and structure of a novel 1-D Mn(II) compound with carboxlyto and imidazole ligands

Share
Edit Delete 报错

author:

Wang, YD (Wang, YD.) [1] | Wu, XH (Wu, XH.) [2] | Zeng, QX (Zeng, QX.) [3] (Scholars:曾庆新) | Unfold

Indexed by:

SCIE PKU CSCD

Abstract:

A novel manganiferous polymeric complex [(imid)(2)(ta)Mn-0.5](n) (imid = imidazole, ta = terephthalato) was synthesized by the hydrothermal reaction of MnO2, terephthalic acid, imidazole, and H2O. Structure analysis indicates that the compound crystallizes in the triclinic system, space group P1, with a = 8.1500(16), b = 8.5100(17), c = 9.0500(18)angstrom, alpha = 72.77(3), beta = 65.50(3), gamma = 77.22(3)degrees, V = 542.02(19) angstrom(3), Z = 2, D-c = 1.505 g/cm(3), F(000) 253, M, = 245.69, mu(MoK alpha) = 0.655 mm(-1), R 0.0733 and wR = 0.1703 for 1673 observed reflections (I > 2 sigma(I)). The compound is characteristic of a zigzag chain-like framework built up of ta bridge and (Imid)(4)Mn group. The 1-D frameworks are held together by H-bonds between the dangling N-H donors from imid and O acceptors from ta.

Keyword:

crystal structure hydrothermal synthesis imidazole terephthalic acid

Community:

  • [ 1 ] Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
  • [ 2 ] Yunnan Univ, Dept Mat Sci & Engn, Kunming 650091, Peoples R China
  • [ 3 ] Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China

Reprint 's Address:

  • 待查

    [Yao, YW]Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China

Show more details

Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2005

Issue: 6

Volume: 24

Page: 641-644

0 . 6 6 9

JCR@2005

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 10

30 Days PV: 1

Online/Total:63/10112115
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1