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[期刊论文]

Preparation of gamma-Fe2O3 support and evaluation of catalytic activty of Ru-K/Fe2O3 catalyst for ammonia synthesis

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author:

Ni Jun (Ni Jun.) [1] (Scholars:倪军) | Wang Rong (Wang Rong.) [2] (Scholars:王榕) | Zheng Ying (Zheng Ying.) [3] | Unfold

Indexed by:

SCIE PKU CSCD

Abstract:

A novel nanometer iron oxide support was successfully synthesized by the sol-gel method. The results of X-ray diffraction, differential thermal analysis, thermogravimetric analysis, scanning electron microscopy, and N-2 physical adsorption show that the prepared Fe2O3 particles have a typical mesoporous structure with pore diameters of 18.8-25.0 nm. The effect of the crystal phase composition of Fe2O3 on catalytic activity of the Ru-K/gamma-Fe2O3 catalyst was further investigated under the conditions of 475 degrees C, 10 MPa, 10000 h(-1), and V(H-2)/ V(N-2) = 3. The higher the content of gamma-Fe2O3 in the support, the better the catalytic activity of the catalyst.

Keyword:

ammonia synthesis mesoporous iron oxide potassium ruthenium sol-gel method support

Community:

  • [ 1 ] Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fujian 350002, Peoples R China
  • [ 2 ] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian 350007, Peoples R China

Reprint 's Address:

  • 倪军

    [Ni Jun]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fujian 350002, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2007

Issue: 1

Volume: 28

Page: 62-66

0 . 5 9 6

JCR@2007

1 5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count:

30 Days PV: 1

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