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[期刊论文]

Preparation of Nanosized Mesoporous CuTSPc/SnO2 and Its Photocatalytic Activity under Visible Light Irradiation

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author:

Guo Longfa (Guo Longfa.) [1] | Pan Haibo (Pan Haibo.) [2] (Scholars:潘海波) | Shen Shuifa (Shen Shuifa.) [3] (Scholars:沈水发) | Unfold

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Scopus SCIE PKU CSCD

Abstract:

Copper tetrasulfonated phthalocyanine (CuTSPc)-sensitized mesoporous SnO2, namely CuTSPc/SnO2, was prepared by a simple template-free hydrothermal method. X-ray diffraction, transmission electron microscopy, N-2 adsorption-desorption, Fourier transform infrared spectroscopy, and UV-Vis spectroscopy were used to characterize the samples. The photocatalytic activity and circulating degradation rate of the photo,catalysts under low-power visible light ( 15 W) were determined using rhodamine B (RhB) as the objective decomposition substance. It was found that the sulfonated groups of CuTSPc are bonded to the tin ion in a chelating bidentate mode in CuTSPc/SnO2, and the specific surface area and pore size for 0.1 mol% CuTSPc/SnO2 are 236 m(2)/g and 2.6 nm, respectively. The degradation rate of RhB with 0.1 mol% CuTSPc/SnO2, is up to 87% during 180 min of reaction.

Keyword:

bonding interaction copper tetrasulfonated phthalocyanine mesopore template-free hydrothermal synthesis tin oxide visible-light photocatalysis

Community:

  • [ 1 ] [Guo Longfa]Fuzhou Univ, Inst Precis Instrument, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Pan Haibo]Fuzhou Univ, Inst Precis Instrument, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Shen Shuifa]Fuzhou Univ, Inst Precis Instrument, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Huang Jinling]Fuzhou Univ, Inst Precis Instrument, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 郭龙发

    [Guo Longfa]Fuzhou Univ, Inst Precis Instrument, Coll Chem & Chem Engn, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2009

Issue: 1

Volume: 30

Page: 53-59

0 . 7 8 6

JCR@2009

1 5 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 3

30 Days PV: 0

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