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author:

Takanabe, Kazuhiro (Takanabe, Kazuhiro.) [1] | Kamata, Kumiko (Kamata, Kumiko.) [2] | Wang, Xinchen (Wang, Xinchen.) [3] (Scholars:王心晨) | Antonietti, Markus (Antonietti, Markus.) [4] | Kubota, Jun (Kubota, Jun.) [5] | Domen, Kazunari (Domen, Kazunari.) [6]

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Scopus SCIE

Abstract:

Spectral sensitization of a mesoporous graphite carbon nitride (mpg-C(3)N(4)) photocatalyst was investigated by depositing magnesium phthalocyanine (MgPc) to expand the absorption to wavelengths longer than those of the principal mpg-C(3)N(4). The obtained sample, MgPc/Pt/mpg-C(3)N(4) (Pt as a cocatalyst) showed stable photocatalytic evolution of hydrogen from aqueous solution in the presence of sacrificial reagents (triethanolamine), even under irradiation at wavelengths longer than 600 nm. Increasing the amount of MgPc led to ordered MgPc aggregation on the photocatalyst surfaces. The rate of photocatalytic hydrogen evolution was highest on a sample with an amount of MgPc corresponding to a monolayer on the Pt/mpg-C(3)N(4) photocatalyst surface. The obtained action spectra of hydrogen evolution and the observation that the amount of evolved hydrogen substantially surpassed the amount of MgPc, confirm that the introduced MgPc functioned as a photocatalytic sensitizer.

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Community:

  • [ 1 ] [Takanabe, Kazuhiro]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 2 ] [Kamata, Kumiko]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 3 ] [Kubota, Jun]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 4 ] [Domen, Kazunari]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 5 ] [Wang, Xinchen]Max Plank Inst Colloids & Interfaces, D-14424 Potsdam, Germany
  • [ 6 ] [Antonietti, Markus]Max Plank Inst Colloids & Interfaces, D-14424 Potsdam, Germany
  • [ 7 ] [Wang, Xinchen]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Domen, Kazunari]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan

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Source :

PHYSICAL CHEMISTRY CHEMICAL PHYSICS

ISSN: 1463-9076

Year: 2010

Issue: 40

Volume: 12

Page: 13020-13025

3 . 4 5 4

JCR@2010

2 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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