Three　polymers　[Zn2(p-CPIDA)(OH)]n　(1),　[Zn2(p-HCPIDA)2(bipy)(H2O)4]center　dot　2H2O　(2),　and　[Zn(m-HCPIDA)(bipy)]n　(3)　[p/m-H3CPIDA　=　N-(4/3-carboxyphenyl)　iminodiacetic　acid,　bipy　=　4,　4　＇-bipyridine]　were　hydrothermally　synthesized　and　characterized　by　single-crystal　X-ray　diffraction,　X-ray　powder　diffraction　patterns　(XPRD),　FTIR　spectroscopy,　and　fluorescence　analyses.　Compound　1　displays　an　interesting　three-dimensional　framework　consisting　of　novel　paddle　wheel　Zn8O10C2　units,　which　are　further　linked　by　p-CPIDA3　ligands　with　versatile　coordination　modes.　In　2,　the　structural　motifs　formed　by　terminal　p-HCPIDA2　ligands　and　ZnII　ions　are　bridged　by　ancillary　bipy　to　give　a　zero-dimensional　Z-shaped　dimer.　Compound　3　has　an　infinite　zigzag　chain　linked　by　bipy,　in　which　terminal　m-HCPIDA2　ligands　alternately　run　along　the　chain　like　flags.　Compounds　2　and　3　are　further　connected　by　hydrogen　bonding　and　pi　center　dot　center　dot　center　dot　pi　stacking　interactions　to　result　in　3D　supramolecular　frameworks.　Moreover,　compounds　13　exhibit　intense　solid　state　fluorescent　emissions　at　room　temperature.