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[期刊论文]

Highly Viscoelastic Worm-Like Micelle Solution of Sodium Hexadecyl Sulfate Induced by Bolaform Counterions

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author:

Zhao Jian-Xi (Zhao Jian-Xi.) [1] (Scholars:赵剑曦) | Yang Duo-Ping (Yang Duo-Ping.) [2]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

The rheological behaviors of mixed aqueous solutions of sodium hexadecyl sulfate (SHS) and a bolaform salt, either N,N'-ethanediyl-alpha,omega-bis(ethyldimethylammonium bromide) (Bola2Et) or N,N'-propanediyl-alpha,omega-bis(trimethylammonium bromide) (Bola4), were investigated by steady-state and frequency-sweep measurements. The results showed that long worm-like micelles were formed in both systems at 45 degrees C, and the solutions exhibited high viscoelasticities, especially the SHS/Bola2Et system in which the solution had very high elasticity. The zero-shear viscosity of SHS/Bola2Et was as high as 2520 Pa . s, and the system was gel-like. These results were attributed to the formation of 2:1 complexes by electrostatic attraction. Since the spacers of both Bola counterions were shorter than the distance between quaternary ammonium ions under electrostatic equilibrium, the generated complex in shape favored formation of worm-like micelles. In comparison, it was difficult to induce SHS to form worm-like micelles by the addition of tetramethylammonium counterions, and the solution exhibited low viscosity.

Keyword:

Anionic surfactant Bola-counterion High viscoelasticity Worm-like micelle

Community:

  • [ 1 ] [Zhao Jian-Xi]Fuzhou Univ, Inst Colloid & Interface Chem, Dept Appl Chem, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Yang Duo-Ping]Fuzhou Univ, Inst Colloid & Interface Chem, Dept Appl Chem, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 赵剑曦

    [Zhao Jian-Xi]Fuzhou Univ, Inst Colloid & Interface Chem, Dept Appl Chem, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China

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Source :

ACTA PHYSICO-CHIMICA SINICA

ISSN: 1000-6818

CN: 11-1892/O6

Year: 2012

Issue: 5

Volume: 28

Page: 1218-1222

0 . 8 6 9

JCR@2012

1 0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 4

30 Days PV: 2

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