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This paper reports a highly stable foam system generated by the gemini surfactant ethanediyl-alpha,omega-bis(tetradecyldimethylammonium bromide) (referred to as 14-2-14). The time measured for the collapse of the foam to half its initial height was used to characterize the foam stability; it was as high as 961 min for this system and significantly longer than that (754 min) for ethanediyl-a,w-bis(dodecyldimethylammonium bromide) (12-2-12) foams. Thus the gemini surfactant structure of;a short spacer together with two long tails enabled it to be a highly efficient foam stabilizer. The dilational rheology of the adsorbed films revealed the relationship between the interfacial elasticity and the foam stability. The high-frequency limit of elasticity of the adsorbed film at a specific surface coverage was again found to indicate foam stability. A larger limit of elasticity indicated a more stable foam.
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ACTA PHYSICO-CHIMICA SINICA
ISSN: 1000-6818
CN: 11-1892/O6
Year: 2012
Issue: 5
Volume: 28
Page: 1213-1217
0 . 8 6 9
JCR@2012
1 0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
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