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author:

Lin Jian-Xin (Lin Jian-Xin.) [1] (Scholars:林建新) | Zhang Liu-Ming (Zhang Liu-Ming.) [2] | Wang Rong (Wang Rong.) [3] (Scholars:王榕) | Ni Jun (Ni Jun.) [4] (Scholars:倪军) | Wei Ke-Mei (Wei Ke-Mei.) [5]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

Ru/CeO2 catalysts were prepared using K2RuO4 and Ce(NO3)(3) as the raw materials by redox methods. The obtained catalysts were characterized by N-2 physisorption, X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), CO chemisorption and temperature-programmed reduction (H-2-TPR). The Ru/CeO2 catalyst prepared by self redox co-precipitation has the largest surface area of 120 m(2).g(-1) and the highest dispersion of 45.6%. The Ru/CeO2 catalyst prepared by self redox co-precipitation shows the best activity, the ammonia concentration in the exit gas reaches 12.6% under the conditions of 10.0 MPa, 425 degrees C, and 10000 h(-1).

Keyword:

ammonia synthesis ceria redox ruthenium

Community:

  • [ 1 ] [Lin Jian-Xin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Zhang Liu-Ming]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang Rong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Ni Jun]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 林建新

    [Lin Jian-Xin]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2012

Issue: 7

Volume: 28

Page: 1377-1382

0 . 7 2

JCR@2012

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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