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The Gd-Bi and the Ho-Bi systems were thermodynamically assessed by CALPHAD (CALculaton of PHAse Diagram) approach based on the available experimental data including thermochemical properties and phase equilibria. The formation enthalpies (at 0 K) of the compounds of the Gd-Bi and the Ho-Bi systems were calculated by the first-principles method and used in the present thermodynamic optimization. The excess Gibbs energies were formulated with the Redlich-Kister polynomial. The intermetallics, Gd5Bi3, Gd4Bi3, GdBi, GdBi2, Ho5Bi3 and HoBi, were treated as stoichiometric compounds. A good agreement between the calculated results and the experimental data was obtained. (C) 2013 Elsevier Ltd. All rights reserved.
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CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
ISSN: 0364-5916
Year: 2013
Volume: 41
Page: 1-5
1 . 3 9 4
JCR@2013
1 . 9 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 20
SCOPUS Cited Count: 11
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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