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[期刊论文]

Reverse atom transfer radical polymerization of styrene in microemulsions catalyzed by CuBr2/Bpy

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author:

Zhang, Weiying (Zhang, Weiying.) [1] (Scholars:张卫英) | Yang, Jing (Yang, Jing.) [2] | Li, Bi'e (Li, Bi'e.) [3] | Unfold

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EI Scopus SCIE

Abstract:

Reverse atom transfer radical polymerization of styrene was carried out in a microemulsion system with 2,2'-azobisisobutyronitrile as initiator, CuBr2 and 2'-bipyridine as catalyst/ligand complex, sodium dodecyl sulfate as emulsifier and 1-hexanol as co-emulsifier. The chosen system showed poor control over molecular weight characteristics, though the low values of polydispersity indexes of the polymer were observed. The particle size was decreased with the increase in the amount of catalyst/ligand complex. Additionally, the nucleation prevailed throughout the polymerization process.

Community:

  • [ 1 ] [Zhang, Weiying]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Yang, Jing]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Li, Bi'e]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Li, Xiao]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Zhang, Weiying]Sichuan Univ, State Key Lab Polymer Mat Engn, Chengdu 610015, Peoples R China
  • [ 6 ] [Dan, Yi]Sichuan Univ, State Key Lab Polymer Mat Engn, Chengdu 610015, Peoples R China

Reprint 's Address:

  • 李晓

    [Li, Xiao]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Peoples R China

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Source :

POLYMER SCIENCE SERIES B

ISSN: 1560-0904

Year: 2013

Issue: 11-12

Volume: 55

Page: 551-555

0 . 6 3 3

JCR@2013

1 . 0 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

30 Days PV: 2

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