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author:

Qian, Xing (Qian, Xing.) [1] (Scholars:钱兴) | Lu, Lin (Lu, Lin.) [2] | Zhu, Yi-Zhou (Zhu, Yi-Zhou.) [3] | Gao, Huan-Huan (Gao, Huan-Huan.) [4] | Zheng, Jian-Yu (Zheng, Jian-Yu.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

A series of zinc porphyrin dyes (JY24-27) featured phenothiazine moieties have been synthesized and applied as photosensitizers in dye-sensitized solar cells. The phenothiazine donors were directly attached to the meso-position of porphyrins, and different pi-linkers (benzene, thiophene and ethynyl benzene) and acceptor groups (carboxylic acid and cyanoacrylic acid) were applied to tune the photoelectric properties of these push-pull porphyrin dyes. The photophysical, electrochemical and theoretical studies revealed that the synthesized porphyrin dyes were all capable of being used as photosensitizer. The dye JY27 with an extended conjugation by introducing ethynyl group exhibited a broader absorption region and more significantly improved IPCE values between 550 and 750 nm than the other three dyes, which ensured a good light-harvesting ability and a high short-circuit current density of 15.3 mA cm (2). Finally, JY27-based cell achieved a high efficiency of 6.25% under standard simulated irradiation.

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Community:

  • [ 1 ] [Qian, Xing]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
  • [ 2 ] [Lu, Lin]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
  • [ 3 ] [Zhu, Yi-Zhou]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
  • [ 4 ] [Gao, Huan-Huan]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
  • [ 5 ] [Zheng, Jian-Yu]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
  • [ 6 ] [Qian, Xing]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China
  • [ 7 ] [Lu, Lin]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China
  • [ 8 ] [Zhu, Yi-Zhou]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China
  • [ 9 ] [Gao, Huan-Huan]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China
  • [ 10 ] [Zheng, Jian-Yu]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China
  • [ 11 ] [Qian, Xing]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Peoples R China
  • [ 12 ] [Zheng, Jian-Yu]Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

Reprint 's Address:

  • [Zhu, Yi-Zhou]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China;;[Zheng, Jian-Yu]Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China;;[Zhu, Yi-Zhou]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China;;[Zheng, Jian-Yu]Nankai Univ, Inst Elemento Organ Chem, Tianjin, Peoples R China;;[Zheng, Jian-Yu]Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

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RSC ADVANCES

ISSN: 2046-2069

Year: 2016

Issue: 11

Volume: 6

Page: 9057-9065

3 . 1 0 8

JCR@2016

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:235

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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