Vinyl　bromides　were　subjected　to　the　trifluoroethoxylation　reactions　with　copper　reagent　[(phen)(2)Cu]　OCH2CF3]　at　80　degrees　C　in　DMF　with　the　presence　of　NaOt-Bu　to　afford　the　trifluoroethyl　vinyl　ethers　in　good　yields.　A　range　of　functional　groups,　such　as　cyano,　nitro,　alkoxy,　trifluoromethyl,　halide,　and　heterocyclic　groups　were　well　tolerated.　This　approach　is　also　amenable　to　being　performed　out　on　gram　scales.　(C)　2016　Elsevier　Ltd.　All　rights　reserved.