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A simple and efficient molecular/solid-state hybrid photocatalyst consisting of noble metal (i.e., Au-III, Pt-IV, and Pd-II) chlorides-functionalized-mesoporous graphitic carbon nitride (mpg-CN) was developed to improve the photocatalytic performance of mpg-CN toward NO removal. Compared with the parent mpg-CN, the optimal 1% PdCl2 modified mpg-CN increased the conversion efficiency by approximately 33%, improved the inhibiting efficiency of NO2 release by approximately three times, and promoted the long term stability of photocatalysts for NO removal in a continuous flow model reaction system. The prepared samples were characterized by X-ray diffraction, transmission electron microscopy with energy-dispersive X-ray spectroscopy elemental mapping, ultraviolet-visible light absorbance spectroscopy, X-ray photoelectron spectroscopy, photoluminescence emission spectroscopy and electron paramagnetic resonance spectroscopy. The ultrafast charge separation and efficient generation of O-2-oxygen species were achieved by the charge transfer model of PdCl2/mpg-CN similar to the solid-state Z-scheme system. This charge transfer model contributed to the high photocatalytic performance of the prepared PdCl2/mpg-CN molecular/solid-state hybrid photocatalyst. (C) 2015 Elsevier B.V. All rights reserved.
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APPLIED CATALYSIS B-ENVIRONMENTAL
ISSN: 0926-3373
Year: 2016
Volume: 184
Page: 174-181
9 . 4 4 6
JCR@2016
2 0 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:235
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 38
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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