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author:

Wang, Kang (Wang, Kang.) [1] | Zhang, Xialan (Zhang, Xialan.) [2] | Zhang, Xinqi (Zhang, Xinqi.) [3] | Chen, Dongyang (Chen, Dongyang.) [4] | Lin, Qilang (Lin, Qilang.) [5] (Scholars:林起浪)

Indexed by:

EI Scopus SCIE

Abstract:

A novel Ni(OH)(2)/graphene nanosheets (GNs) composite with Ni(OH)(2) nanoflakes dispersing within a 3D fluffy and conductive graphene network has been successfully prepared by a facile hydrothermal reaction for pseudocapacitor applications. Using the as-prepared Ni(OH)(2)/GNs composite as active material, the pseudocapacitor electrode exhibits very high capacitance and encouraging rate capability, as indicated by the experimental results that its specific capacitance is 2260 F g(-1) at a current density of 1 A g(-1) and 1401 F g(-1) when the current density is increased to 10 A g(-1) (61.9% retention). In addition, its shows remarkable long-term cycling stability, with a high capacitance retention of 115.6% at 100 mV s(-1) after 4000 cycles and only 2.6% of decay at a current density of 16 A g(-1) over 1000 cycles. The excellent electrochemical performance of the Ni(OH)(2)/GNs composite electrode is ascribed to its enhanced ion and electron transport kinetic arising from its unique microstructure, namely a 3D electron conductive graphene network with ion diffusive fluffy pathways. Therefore, the Ni(OH)2/GNs composite electrode is a promising candidate for high performance pseudocapacitors; the fluffy crystalline GNs are promising matrix for advanced energy materials with ensured ion and electron conductivities. (C) 2016 Elsevier B.V. All rights reserved.

Keyword:

Fluffy graphene sheets Nanocomposite Nickel hydroxide Pesudocapacitor

Community:

  • [ 1 ] [Wang, Kang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Zhang, Xialan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Zhang, Xinqi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 4 ] [Chen, Dongyang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Lin, Qilang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 陈栋阳 林起浪

    [Chen, Dongyang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China;;[Lin, Qilang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2016

Volume: 333

Page: 156-163

6 . 3 9 5

JCR@2016

8 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:324

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 48

SCOPUS Cited Count: 50

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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