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author:

Li, Mengpei (Li, Mengpei.) [1] | Chen, Qidi (Chen, Qidi.) [2] (Scholars:陈奇俤) | Zhan, Hongbing (Zhan, Hongbing.) [3] (Scholars:詹红兵)

Indexed by:

EI Scopus SCIE

Abstract:

In this work, N-doped carbon nanotubes (NCNTS) have been easily unzipped using a chemical oxidation method to obtain porous and multi-defective partially unzipped N-doped carbon nanotubes (PU-NCNTs), which are promising as negative electrode materials for supercapacitors and are also suitable substrate materials for the efficient loading of ultrathin manganese dioxide (MnO2) nanosheets. Herein, the PU-NCNT/MnO2 composite was synthesized through a simple microwave irradiation method. Moreover, we have fabricated an asymmetric supercapacitor (ASC) using PU-NCNT/MnO2 composite as cathode, PU-NCNTs as anode and neutral aqueous Na2SO4 as electrolyte. Because of the synergistic effects of the PU-NCNTs electrode and the high capacitance as well as good rate performance of PU-NCNT/MnO2 composite, the asymmetric cell exhibited good electrochemical performance. The optimized ASC can be worked stably in the voltage window of 0-1.8 V and exhibited a maximum energy density of 14.76 Wh kg(-1) at the current density of 1 A g(-1). Additionally, the PU-NCNT/MnO2//PU-NCNT ASC exhibited long cycling stability with 80.5% specific capacitance retained after 1000 cycles at a current density of 1 A These encouraging results show that PU-NCNT/MnO2 could be promising materials for commercial use of supercapacitors. (C) 2017 Elsevier B.V. All rights reserved.

Keyword:

Microwave method MnO2 Partially unzipped N-doped carbon nanotubes Supercapacitor

Community:

  • [ 1 ] [Li, Mengpei]Fuzhou Univ, Coll Mat Sci & Engn, 2 Xueyuan Rd, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Chen, Qidi]Fuzhou Univ, Coll Mat Sci & Engn, 2 Xueyuan Rd, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Zhan, Hongbing]Fuzhou Univ, Coll Mat Sci & Engn, 2 Xueyuan Rd, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 詹红兵

    [Zhan, Hongbing]Fuzhou Univ, Coll Mat Sci & Engn, 2 Xueyuan Rd, Fuzhou 350116, Fujian, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2017

Volume: 702

Page: 236-243

3 . 7 7 9

JCR@2017

5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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