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author:

Kessler, Fabian K. (Kessler, Fabian K..) [1] | Zheng, Yun (Zheng, Yun.) [2] | Schwarz, Dana (Schwarz, Dana.) [3] | Merschjann, Christoph (Merschjann, Christoph.) [4] | Schnick, Wolfgang (Schnick, Wolfgang.) [5] | Wang, Xinchen (Wang, Xinchen.) [6] (Scholars:王心晨) | Bojdys, Michael J. (Bojdys, Michael J..) [7]

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Scopus SCIE

Abstract:

In the past decade, research in the field of artificial photosynthesis has shifted from simple, inorganic semiconductors to more abundant, polymeric materials. For example, polymeric carbon nitrides have emerged as promising materials for metal-free semiconductors and metal-free photocatalysts. Polymeric carbon nitride (melon) and related carbon nitride materials are desirable alternatives to industrially used catalysts because they are easily synthesized from abundant and inexpensive starting materials. Furthermore, these materials are chemically benign because they do not contain heavy metal ions, thereby facilitating handling and disposal. In this Review, we discuss the building blocks of carbon nitride materials and examine how strategies in synthesis, templating and post-processing translate from the molecular level to macroscopic properties, such as optical and electronic bandgap. Applications of carbon nitride materials in bulk heterojunctions, laser-patterned memory devices and energy storage devices indicate that photocatalytic overall water splitting on an industrial scale may be realized in the near future and reveal a new avenue of 'post-silicon electronics'.

Keyword:

Community:

  • [ 1 ] [Kessler, Fabian K.]Univ Munich LMU, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany
  • [ 2 ] [Schnick, Wolfgang]Univ Munich LMU, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany
  • [ 3 ] [Zheng, Yun]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Schwarz, Dana]Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 8, Prague 12843 2, Czech Republic
  • [ 6 ] [Bojdys, Michael J.]Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 8, Prague 12843 2, Czech Republic
  • [ 7 ] [Merschjann, Christoph]Free Univ Berlin, Fachbereich Phys, Arnimallee 14, D-14195 Berlin, Germany
  • [ 8 ] [Bojdys, Michael J.]ASCR VVI, Inst Organ Chem & Biochem, Flemingovo Nam 2, Prague 16610 6, Czech Republic

Reprint 's Address:

  • [Bojdys, Michael J.]Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 8, Prague 12843 2, Czech Republic;;[Bojdys, Michael J.]ASCR VVI, Inst Organ Chem & Biochem, Flemingovo Nam 2, Prague 16610 6, Czech Republic

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Source :

NATURE REVIEWS MATERIALS

ISSN: 2058-8437

Year: 2017

Issue: 6

Volume: 2

5 1 . 9 4 1

JCR@2017

7 9 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 650

SCOPUS Cited Count: 653

ESI Highly Cited Papers on the List: 38 Unfold All

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