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author:

Chen, Qidi (Chen, Qidi.) [1] (Scholars:陈奇俤) | Miao, Jinkang (Miao, Jinkang.) [2] | Quan, Liang (Quan, Liang.) [3] | Cai, Daoping (Cai, Daoping.) [4] (Scholars:蔡道平) | Zhan, Hongbing (Zhan, Hongbing.) [5] (Scholars:詹红兵)

Indexed by:

EI Scopus SCIE

Abstract:

Exploring high-performance and low-priced electrode materials for supercapacitors is important but remains challenging. In this work, a unique sandwich-like nanocomposite of reduced graphene oxide (rGO)-supported N-doped carbon embedded with ultrasmall CoNiSx nanocrystallites (rGO/CoNiSx/N-C nanocomposite) has been successfully designed and synthesized by a simple one-step carbonization/sulfurization treatment of the rGO/Co-Ni precursor. The intriguing structural/compositional/morphological advantages endow the as-synthesized rGO/CoNiSx/N-C nanocomposite with excellent electrochemical performance as an advanced electrode material for supercapacitors. Compared with the other two rGO/CoNiOx and rGO/CoNiSx nanocomposites, the rGO/CoNiSx/N-C nanocomposite exhibits much enhanced performance, including a high specific capacitance (1028.2 F g(-1) at 1 A g(-1)), excellent rate capability (89.3% capacitance retention at 10 A g(-1)) and good cycling stability (93.6% capacitance retention over 2000 cycles). In addition, an asymmetric supercapacitor (ASC) device based on the rGO/CoNiSx/N-C nanocomposite as the cathode and activated carbon (AC) as the anode is also fabricated, which can deliver a high energy density of 32.9 W h kg(-1) at a power density of 229.2 W kg(-1) with desirable cycling stability. These electrochemical results evidently indicate the great potential of the sandwich-like rGO/CoNiSx/N-C nanocomposite for applications in high-performance supercapacitors.

Keyword:

Community:

  • [ 1 ] [Chen, Qidi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Miao, Jinkang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Quan, Liang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Cai, Daoping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Zhan, Hongbing]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Zhan, Hongbing]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 蔡道平 詹红兵

    [Cai, Daoping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China;;[Zhan, Hongbing]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China;;[Zhan, Hongbing]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350116, Fujian, Peoples R China

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Source :

NANOSCALE

ISSN: 2040-3364

Year: 2018

Issue: 8

Volume: 10

Page: 4051-4060

6 . 9 7

JCR@2018

5 . 8 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:158

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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