• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Zhang, Bo (Zhang, Bo.) [1] | Zhong, Zhibing (Zhong, Zhibing.) [2] | Tu, Taiping (Tu, Taiping.) [3] | Wu, Kewen (Wu, Kewen.) [4] | Peng, Kaiping (Peng, Kaiping.) [5] (Scholars:彭开萍)

Indexed by:

EI Scopus SCIE

Abstract:

In the present work, La1.9M0.1Ce2O7 (M = Nd, Sm, Dy, Y, In) powders are synthesized by citric acid-nitrate solgel combustion method. The effects of the acceptor dopant on the phase structure, microstructure and electrical properties of La1.9M0.1Ce2O7 ceramics are investigated. All La1.9M0.1Ce2O7 ceramics possess a single-phase fluorite structure. It turns out that the In-doped ceramic exhibits the highest electrical conductivity of 0.82 x 10(-2) and 2.03 x 10(-25) cm(-1) at 700 degrees C both in dry air and wet 5% H-2 Ar atmospheres, respectively. Furthermore, in order to eliminate the internal short circuit resulting from the reduction of Ce4+ to Ce3+, a novel Ni-BaCe0.5Zr0.3Dy0.2O3.8 composite is applied and evaluated as the anode for the fuel cell based on La1.9M0.1Ce2O7 electrolyte. Raman and scanning electron microscope and energy dispersive spectrometer analyses indicate that a Ba-containing electron-blocking layer is formed in-situ at the anode/electrolyte interface. The new structured fuel cell with Ni-BaCe0.5Zr0.3Dy0.2O3-delta anode and La1.9In0.1Ce2 O-7 electrolyte exhibit significantly improved open circuit voltage of 1.005 V along with maximum power density of 546 mW cm(-2) at 700 degrees C using humidified hydrogen fuel. The results demonstrate that La1.9In0.1Ce2O7 electrolyte and Ni-BaCe0.5Zr0.3Dy0.2O3-delta anode can be considered as the promising candidates for solid oxide fuel cells applications.

Keyword:

Conductivity Electron-blocking layer La2Ce2O7 Solid oxide fuel cells

Community:

  • [ 1 ] [Zhang, Bo]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Zhong, Zhibing]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Tu, Taiping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Wu, Kewen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Peng, Kaiping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 彭开萍

    [Peng, Kaiping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China

Show more details

Related Keywords:

Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2019

Volume: 412

Page: 631-639

8 . 2 4 7

JCR@2019

8 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 28

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:165/10010569
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1