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author:

Xiang, Xiaoqiang (Xiang, Xiaoqiang.) [1] | Lin, Hang (Lin, Hang.) [2] | Li, Renfu (Li, Renfu.) [3] | Cheng, Yao (Cheng, Yao.) [4] | Huang, Qingming (Huang, Qingming.) [5] (Scholars:黄清明) | Xu, Ju (Xu, Ju.) [6] | Wang, Congyong (Wang, Congyong.) [7] | Chen, Xueyuan (Chen, Xueyuan.) [8] | Wang, Yuansheng (Wang, Yuansheng.) [9]

Indexed by:

Scopus SCIE CSCD

Abstract:

In this work, we discovered an unexpected mechanoluminescence (ML) phenomena occurring when transforming amorphous into crystalline, due to the stress-induced precipitation of CsPbBr3 perovskite nanocrystals on glass surface. It is revealed that, unlike the conventional thermal-induced phase transformation mechanism, the breakage of bonding of glass network provides the energy for nucleation and growth, and the shear stress avoids the long-range migration of structural units for crystallization. Such unique ML phenomenon enables the visualization of dynamical force that is inaccessible by common strategy, and so, opens up some novel applications, such as the pressuresensitive glassy pencil to learn people's writing habits, and the Pb2+-detection with good sensitivity and selectivity. These findings not only demonstrate an effective route for the preparation of perovskite materials in a green, time-saving, low cost, and scalable way, enrich the knowledge of glass crystallization mechanism, but also exploit a useful avenue to quantitatively visualize the dynamical force.

Keyword:

CsPbBr3 glass ceramics mechanoluminescence nanocrystallization perovskite nanocrystals

Community:

  • [ 1 ] [Xiang, Xiaoqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 2 ] [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 3 ] [Li, Renfu]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 4 ] [Cheng, Yao]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 5 ] [Xu, Ju]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 6 ] [Wang, Congyong]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 7 ] [Chen, Xueyuan]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 8 ] [Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 9 ] [Xiang, Xiaoqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 10 ] [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 11 ] [Li, Renfu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 12 ] [Cheng, Yao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 13 ] [Xu, Ju]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 14 ] [Wang, Congyong]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 15 ] [Chen, Xueyuan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 16 ] [Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 17 ] [Xiang, Xiaoqiang]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Fujian, Peoples R China
  • [ 18 ] [Huang, Qingming]Fuzhou Univ, Instrumentat Anal & Res Ctr, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China;;[Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China;;[Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China;;[Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Peoples R China

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Source :

NANO RESEARCH

ISSN: 1998-0124

Year: 2019

Issue: 5

Volume: 12

Page: 1049-1054

8 . 1 8 3

JCR@2019

9 . 6 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:138

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 50

SCOPUS Cited Count: 60

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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