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author:

Ye, Yuanyao (Ye, Yuanyao.) [1] | Jiao, Jie (Jiao, Jie.) [2] | Kang, Dejun (Kang, Dejun.) [3] (Scholars:康得军) | Jiang, Wei (Jiang, Wei.) [4] | Kang, Jianxiong (Kang, Jianxiong.) [5] | Huu Hao Ngo (Huu Hao Ngo.) [6] | Guo, Wenshan (Guo, Wenshan.) [7] | Liu, Yiwen (Liu, Yiwen.) [8]

Indexed by:

Scopus SCIE

Abstract:

A magnesia-pullulan (MgOP) composite has been developed to remove phosphate from a synthetic solution. In the present study, the removal of phosphate by MgOP was evaluated in both a batch and dynamic system. The batch experiments investigated the initial pH effect on the phosphate removal efficiency from pH3 to 12 and the effect of co-existing anions. In addition, the adsorption isotherms, thermodynamics, and kinetics were also investigated. The results from the batch experiments indicate that MgOP has encouraging performance for the adsorption of phosphate, while the initial pH value (3-12) had a negligible influence on the phosphate removal efficiency. Analysis of the adsorption thermodynamics demonstrated that the phosphate removal process was endothermic and spontaneous. Investigations into the dynamics of the phosphate removal process were carried out using a fixed bed of MgOP, and the resulting breakthrough curves were used to describe the column phosphate adsorption process at various bed masses, volumetric flow rates, influent phosphate concentrations, reaction temperatures, and inlet pH values. The results suggest that the adsorption of phosphate on MgOP was improved using an increased bed mass, while the reaction temperature did not significantly affect the performance of the MgOP bed during the phosphate removal process. Furthermore, higher influent phosphate concentrations were beneficial towards increasing the column adsorption capacity for phosphate. Several mathematic models, including the Adams-Bohart, Wolboska, Yoon-Nelson, and Thomas models, were employed to fit the fixed-bed data. In addition, the effluent concentration of magnesium ions was measured and the regeneration of MgOP investigated.

Keyword:

Adsorption Breakthrough curve Column experiments Phosphate Regeneration

Community:

  • [ 1 ] [Jiang, Wei]Huazhong Univ Sci & Technol, Sch Environm Sci & Engn, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China
  • [ 2 ] [Kang, Jianxiong]Huazhong Univ Sci & Technol, Sch Environm Sci & Engn, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China
  • [ 3 ] [Ye, Yuanyao]Univ Technol Sydney, Sch Civil & Environm Engn, Ctr Technol Water & Wastewater, Sydney, NSW 2007, Australia
  • [ 4 ] [Huu Hao Ngo]Univ Technol Sydney, Sch Civil & Environm Engn, Ctr Technol Water & Wastewater, Sydney, NSW 2007, Australia
  • [ 5 ] [Guo, Wenshan]Univ Technol Sydney, Sch Civil & Environm Engn, Ctr Technol Water & Wastewater, Sydney, NSW 2007, Australia
  • [ 6 ] [Liu, Yiwen]Univ Technol Sydney, Sch Civil & Environm Engn, Ctr Technol Water & Wastewater, Sydney, NSW 2007, Australia
  • [ 7 ] [Jiao, Jie]Wisdri City Environm Protect Engn Co Ltd, Wuhan, Hubei, Peoples R China
  • [ 8 ] [Kang, Dejun]Fuzhou Univ, Dept Municipal Engn, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • [Jiang, Wei]Huazhong Univ Sci & Technol, Sch Environm Sci & Engn, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China

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Source :

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH

ISSN: 0944-1344

Year: 2019

Issue: 13

Volume: 26

Page: 13299-13310

3 . 0 5 6

JCR@2019

0 . 0 0 0

JCR@2023

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:188

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 16

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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