Herein,　a　facile　reorganization　of　a　triazine-based　conjugated　polymer　structure　was　adopted　to　optimize　the　optical,　electronic,　and　photocatalytic　properties　of　the　polymer.　The　optimal　photocatalyst　presents　enhanced　performance　as　compared　to　the　pristine　photocatalyst　by　a　factor　of　3.　This　demonstration　provides　a　new　strategy　for　the　optimization　of　conjugated　polymers　for　various　photoredox　applications.