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Abstract:
To reduce greenhouse effects, reduction of CO2 in solid oxide electrolyser has attracted considerable attentions. Herein, a series of metallic nickel cathodes with in situ grown Cr2O3-delta nano-islands are developed for CO2 electrolysis at high temperature. Enhanced CO2 chemisorption is observed with distributed Cr2O3-delta nanoparticles on porous nickel backbone while the adsorption mechanism is discussed. The optimal current density of 2.07 A cm(-2) is harvested when using Ni/12.20% Cr2O3-delta as cathode in CO2/CO atmosphere at 800 degrees C and 1.6 V. Long-term stability is achieved for either CO2/CO or pure CO2 electrolysis even after high-temperature operation of 50 h, indicating that the Ni/Cr2O3-delta would be an attractive cathode for CO2 electrolysis at high temperature.
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JOURNAL OF POWER SOURCES
ISSN: 0378-7753
Year: 2019
Volume: 430
Page: 20-24
8 . 2 4 7
JCR@2019
8 . 1 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:236
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 18
SCOPUS Cited Count: 20
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: