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author:

Hu, Xiuli (Hu, Xiuli.) [1] | Xie, Kui (Xie, Kui.) [2]

Indexed by:

EI Scopus SCIE

Abstract:

To reduce greenhouse effects, reduction of CO2 in solid oxide electrolyser has attracted considerable attentions. Herein, a series of metallic nickel cathodes with in situ grown Cr2O3-delta nano-islands are developed for CO2 electrolysis at high temperature. Enhanced CO2 chemisorption is observed with distributed Cr2O3-delta nanoparticles on porous nickel backbone while the adsorption mechanism is discussed. The optimal current density of 2.07 A cm(-2) is harvested when using Ni/12.20% Cr2O3-delta as cathode in CO2/CO atmosphere at 800 degrees C and 1.6 V. Long-term stability is achieved for either CO2/CO or pure CO2 electrolysis even after high-temperature operation of 50 h, indicating that the Ni/Cr2O3-delta would be an attractive cathode for CO2 electrolysis at high temperature.

Keyword:

Carbon dioxide Cathode Metal-oxide interface Solid oxide electrolyser

Community:

  • [ 1 ] [Hu, Xiuli]Fuzhou Univ, Coll Chem, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Hu, Xiuli]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Xie, Kui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Xie, Kui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2019

Volume: 430

Page: 20-24

8 . 2 4 7

JCR@2019

8 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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