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author:

Li, Jian-Hua (Li, Jian-Hua.) [1] (Scholars:李建华) | Zheng, Hui (Zheng, Hui.) [2] | Lin, Hua-Xiang (Lin, Hua-Xiang.) [3] (Scholars:林华香) | Zhang, Bo-Xin (Zhang, Bo-Xin.) [4] | Wang, Jia-Bin (Wang, Jia-Bin.) [5] | Li, Tong-Lei (Li, Tong-Lei.) [6] | Zhang, Qi-Qing (Zhang, Qi-Qing.) [7]

Indexed by:

Scopus SCIE CSCD

Abstract:

In this work, poly(vinylidene fluoride) (PVDF) membranes with hydrophilicity as well as preeminent mechanical strength and dye removal efficiency were fabricated by blending with three dimensional hydroxyapatite nanoparticles (HAPNPs). Surface chemical composition and morphology of the prepared membranes were systematically investigated by ATR-FTIR, XPS, XRD, FESEM, and EDS mapping analyses. The results verified that a large number of HAPNPs were successfully embedded on the modified membrane cross-sections. Moreover, HAPNPs content in the casting solution is an important factor that could have profound influence on the structures and performances of PVDF/HAPNPs blend membranes. The optimal membrane M2 with 2 wt% HAPNPs exhibited excellent hydrophilicity, outstanding mechanical strength of 19.60 MPa, and high water flux of (2466 +/- 31) Lm(-2)h(-1). The maximum static adsorption capacity of the optimal membrane was about 10.83 mg/g, which is 3.75 times that of the pristine PVDF membrane (2.89 mg/g). PVDF/HAPNPs membranes were not only utilized for static adsorption, but also applied to dynamic dye removal. The possible adsorption mechanism between Congo red (CR) and HAPNPs embedded on the blend membranes was firstly discussed in this work. HAPNPs interacted with CR via Lewis reaction, hydrogen bond interaction, as well as electrostatic attraction to achieve the adsorption effect. Herein, the PVDF/HAPNPs blend membranes with extraordinary hydrophilicity, mechanical strength, and dye removal efficiency possess tremendous potential for practical applications of wastewater treatment.

Keyword:

Adsorption mechanism Dynamic dye removal HAPNPs blend membranes Mechanical strength PVDF Three dimensional hydroxyapatite nanoparticles

Community:

  • [ 1 ] [Li, Jian-Hua]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Fujian, Peoples R China
  • [ 2 ] [Zheng, Hui]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Fujian, Peoples R China
  • [ 3 ] [Zhang, Bo-Xin]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Fujian, Peoples R China
  • [ 4 ] [Wang, Jia-Bin]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Fujian, Peoples R China
  • [ 5 ] [Zhang, Qi-Qing]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Fujian, Peoples R China
  • [ 6 ] [Lin, Hua-Xiang]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 7 ] [Li, Tong-Lei]Purdue Univ, Dept Ind & Phys Pharm, 575 Stadium Mall Dr, W Lafayette, IN 47906 USA

Reprint 's Address:

  • 李建华

    [Li, Jian-Hua]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Fujian, Peoples R China

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Source :

CHINESE JOURNAL OF POLYMER SCIENCE

ISSN: 0256-7679

CN: 11-2015/O6

Year: 2019

Issue: 12

Volume: 37

Page: 1234-1247

3 . 1 5 4

JCR@2019

4 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 13

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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