A　kind　of　nitrogen-doped　carbon　(NC)　nanomaterials　was　prepared　via　calcining　the　nitrogen-rich　organic　molecular　glycoluril　under　nitrogen　atmosphere.　Elemental　analysis　result　indicates　the　N　content　of　the　obtained　NC　is　13.9　wt.%.　Electrochemical　measurement　demonstrated　that　the　obtained　NC　catalyst　is　an　efficient　ORR　electrocatalyst　in　alkaline　electrolyte.　The　process　of　ORR　is　dominated　by　a　four-electron　transfer　pathway　with　the　most　efficient　catalytic　activity.　In　addition,　the　NC　catalyst　exhibits　excellent　stability　and　good　resistance　to　methanol　poisoning.　After　10000　s　of　chronoamperometric　durability　test,　the　relative　current　of　NC　catalyst　retained　as　high　as　95%.　This　work　provides　a　new　strategy　for　the　preparation　of　cost-effective　ORR　catalysts　with　high　catalytic　performance.