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author:

Ullah, Azeem (Ullah, Azeem.) [1] | Khan, Javid (Khan, Javid.) [2] | Sohail, Muhammad (Sohail, Muhammad.) [3] | Hayat, Asif (Hayat, Asif.) [4] | Zhao, Ting Kai (Zhao, Ting Kai.) [5] | Ullah, Bakhtar (Ullah, Bakhtar.) [6] | Khan, Muhammad (Khan, Muhammad.) [7] | Uddin, Ikram (Uddin, Ikram.) [8] | Ullah, Saif (Ullah, Saif.) [9] | Ullah, Rooh (Ullah, Rooh.) [10] | Rehman, Ata Ur (Rehman, Ata Ur.) [11] | Khan, Wasim Ullah (Khan, Wasim Ullah.) [12]

Indexed by:

Scopus SCIE

Abstract:

Utilization of solar heat radiation into chemical energy is attributed to semiconductor photocatalyst under sunlight perspective considered as a reversing inspired approach that exacerbates the environmental problems. Recently, our group indicates graphitic carbon nitride (g-CN) by a progressive molecular aggregation co-polymerization process that propagated with a nanoscopic organic conjugated heterocyclic monomer to enhance its photocatalytic activity. This work aims to present a facile induced co-condensation technique and used 2, 6-Furandicarboxylic acid (FA) monomer as demonstrator within g-CN that boosting the photocatalytic properties under solar energy driven caused the reduction of water. The as-prepared samples were demonstrated for various characterizations along with computational evaluation of pure and doped g-CN. The result signifying the integration of organic FA monomer in the triazine core shell of g-CN restoring a substantial delocalization in its pi-conjugated system. Meanwhile, after this alternation, an identifiable undulation occurred in the surface area, electronic structure, calculated band gap, chemical composition analysis of g-CN, and also improved its electronic generation process under the visible light radiance. Besides, this unrepeatable integrity of FA co-monomer with ing-CN matrix considerably enhanced the photocatalytic activity toward Godspeed and as such, the superior photocatalyst CN/FA(12.0) stimulated a tremendous photocatalytic activity of water reduction with 10.6 enhanced catalytic performances as a contrast of pristine sample respectively.

Keyword:

2, 6-Furandicarboxylic acid (FA) monomer Co-polymerization Graphitic carbon nitride (g-CN) Photocatalysis Water reduction (HER)

Community:

  • [ 1 ] [Ullah, Azeem]Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
  • [ 2 ] [Zhao, Ting Kai]Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
  • [ 3 ] [Khan, Muhammad]Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China
  • [ 4 ] [Ullah, Azeem]Northwestern Polytech Univ, NPU NCP Joint Int Res Ctr Adv Nanomat & Defects E, Xian 710072, Shaanxi, Peoples R China
  • [ 5 ] [Zhao, Ting Kai]Northwestern Polytech Univ, NPU NCP Joint Int Res Ctr Adv Nanomat & Defects E, Xian 710072, Shaanxi, Peoples R China
  • [ 6 ] [Khan, Muhammad]Northwestern Polytech Univ, NPU NCP Joint Int Res Ctr Adv Nanomat & Defects E, Xian 710072, Shaanxi, Peoples R China
  • [ 7 ] [Khan, Javid]Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Peoples R China
  • [ 8 ] [Khan, Wasim Ullah]Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Peoples R China
  • [ 9 ] [Sohail, Muhammad]Shenzhen Univ, Inst Adv Study, Shenzhen 518060, Peoples R China
  • [ 10 ] [Ullah, Bakhtar]Shenzhen Univ, Inst Adv Study, Shenzhen 518060, Peoples R China
  • [ 11 ] [Hayat, Asif]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 12 ] [Uddin, Ikram]Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China
  • [ 13 ] [Ullah, Saif]Anhui Univ, Dept Chem, Hefei 230601, Peoples R China
  • [ 14 ] [Ullah, Rooh]Univ Turbat, Dept Chem, Baluchistan 92600, Pakistan
  • [ 15 ] [Rehman, Ata Ur]Northwest Univ, Sch Chem Engn, Xian, Pakistan

Reprint 's Address:

  • ASIF HAYAT

    [Zhao, Ting Kai]Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian 710072, Shaanxi, Peoples R China;;[Hayat, Asif]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China

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Source :

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

ISSN: 1010-6030

Year: 2020

Volume: 401

4 . 2 9 1

JCR@2020

4 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 48

SCOPUS Cited Count: 48

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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