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author:

Mishina, Tomohiro (Mishina, Tomohiro.) [1] | Fujiwara, Naoya (Fujiwara, Naoya.) [2] | Tada, Shohei (Tada, Shohei.) [3] | Takagaki, Atsushi (Takagaki, Atsushi.) [4] | Kikuchi, Ryuji (Kikuchi, Ryuji.) [5] | Oyama, Shigeo Ted (Oyama, Shigeo Ted.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

Direct internal reforming is one of the promising methods of utilizing hydrocarbon fuels in solid oxide fuel cells (SOFCs). Among direct internal reforming technologies, dry reforming of methane (DRM) is attracting attention as an alternative to steam reforming of methane. In this study, a cermet material composed of nickel and samarium-doped ceria (Ni-SDC) was investigated as an SOFC anode for the direct internal DRM operation. Compared to a conventional nickel-yttria-stabilized zirconia (Ni-YSZ) anode, the Ni-SDC anode showed superior current-voltage characteristics. However, poor carbon balances were recorded in anode outlet gas analysis, indicating coke formation on the Ni-SDC anode. The addition of calcium to the Ni-SDC anode was also tested. Measured anode outlet gas compositions suggested that the calcium addition suppressed coke formation, while the power generation performance of the pristine Ni-SDC anode was maintained. Microscopic observations showed that a certain part of the calcium additive existed as CaO particles on the anode surface, which could be responsible for the improved coking resistance.

Keyword:

Direct internal reforming Dry reforming of methane Ni-SDC anode Solid oxide fuel cell

Community:

  • [ 1 ] [Mishina, Tomohiro]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 2 ] [Fujiwara, Naoya]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 3 ] [Kikuchi, Ryuji]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
  • [ 4 ] [Tada, Shohei]Ibaraki Univ, Dept Mat Sci & Engn, Hitachi, Ibaraki 3168511, Japan
  • [ 5 ] [Takagaki, Atsushi]Kyushu Univ, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
  • [ 6 ] [Oyama, Shigeo Ted]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 7 ] [Oyama, Shigeo Ted]Virginia Tech, Dept Chem Engn, Blacksburg, VA 24061 USA

Reprint 's Address:

  • [Kikuchi, Ryuji]Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan

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Source :

JOURNAL OF THE ELECTROCHEMICAL SOCIETY

ISSN: 0013-4651

Year: 2020

Issue: 13

Volume: 167

4 . 3 1 6

JCR@2020

3 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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