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author:

Zeng, Jie (Zeng, Jie.) [1] | Han, Guilin (Han, Guilin.) [2] | Wu, Qixin (Wu, Qixin.) [3] | Qu, Rui (Qu, Rui.) [4] | Ma, Qing (Ma, Qing.) [5] | Chen, Jingwen (Chen, Jingwen.) [6] | Mao, Shijun (Mao, Shijun.) [7] | Ge, Xin (Ge, Xin.) [8] | Wang, Zhong-Jun (Wang, Zhong-Jun.) [9] | Ma, Zhiheng (Ma, Zhiheng.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

The coastal urban region is generally considered an atmospheric receptor for terrestrial and marine input materials, and rainfall chemistry can trace the wet scavenging process of these materials. Fast urbanization in China's east coastal areas has greatly altered the rainwater chemistry. However, the chemical variations, determinants, and sources of rainfall are unclear. Therefore, the typical coastal city of Fuzhou was selected for 1-year rainwater sampling and inorganic ions were detected to explore above problems. The findings depicted that rainwater ions in Fuzhou were slightly different from those in other coastal cities. Although NO3-, SO42-, Ca2+ and NH4+ dominated the rainwater ions, the marine input Cl- (22 %) and Na+ (11 %) also contributed a considerable percentage to the rainwater ions. Large differences in ion concentrations (2 similar to 28 times) were found in monthly scale due to the rainfall amount. Both natural and anthropogenic determinants influenced the rainwater ions in coastal cities, such as SO2 emission, air SO2 and PM10 content on rainwater SO42-, NO3-, and Ca2+, and soot & dust emission on rainwater SO42-, NO3-, indicating the vital contribution of human activities. Stoichiometry and positive matrix factorization-based sources identification indicated that atmospheric dust/particles were the primary contributor of Ca2+ (83.3 %) and F- (83.7 %), and considerable contributor of SO42- (39.5 %), NO3- (38.3 %) and K+ (41.5 %). Anthropogenic origins, such as urban waste volatilization and fuel combustion emission, contributed 95 % of NH4+, 54.5 % of NO3- and 41.9 % of SO42-, and the traffic sources contribution was relatively higher than fixed emission sources. The marine input represented the vital source of Cl- (77.7 %), Na+ (84.9 %), and Mg2+ (55.3 %). This work highlights the significant influence of urban human activities and marine input on rainwater chemicals and provides new insight into the material cycle between the atmosphere and earth-surface in coastal city.

Keyword:

Anthropogenic and marine input Coastal city Determinants Rainwater chemistry Source identification

Community:

  • [ 1 ] [Zeng, Jie]Guizhou Univ, Coll Resources & Environm Engn, Minist Educ, Key Lab Karst Georesources & Environm, Guiyang 550025, Peoples R China
  • [ 2 ] [Wu, Qixin]Guizhou Univ, Coll Resources & Environm Engn, Minist Educ, Key Lab Karst Georesources & Environm, Guiyang 550025, Peoples R China
  • [ 3 ] [Ma, Qing]Guizhou Univ, Coll Resources & Environm Engn, Minist Educ, Key Lab Karst Georesources & Environm, Guiyang 550025, Peoples R China
  • [ 4 ] [Ge, Xin]Guizhou Univ, Coll Resources & Environm Engn, Minist Educ, Key Lab Karst Georesources & Environm, Guiyang 550025, Peoples R China
  • [ 5 ] [Zeng, Jie]Guizhou Univ, North Alabama Int Coll Engn & Technol, Guiyang 550025, Peoples R China
  • [ 6 ] [Wu, Qixin]Guizhou Univ, North Alabama Int Coll Engn & Technol, Guiyang 550025, Peoples R China
  • [ 7 ] [Mao, Shijun]Guizhou Univ, North Alabama Int Coll Engn & Technol, Guiyang 550025, Peoples R China
  • [ 8 ] [Han, Guilin]China Univ Geosci Beijing, State Key Lab Biogeol & Environm Geol, Beijing 100083, Peoples R China
  • [ 9 ] [Qu, Rui]China Univ Geosci Beijing, State Key Lab Biogeol & Environm Geol, Beijing 100083, Peoples R China
  • [ 10 ] [Chen, Jingwen]Fuzhou Univ, Fujian Key Lab Mineral Resources, Fuzhou 350108, Peoples R China
  • [ 11 ] [Wang, Zhong-Jun]Yancheng Inst Technol, Sch Environm Sci & Engn, Yancheng 224051, Peoples R China
  • [ 12 ] [Ma, Zhiheng]Southwest Petr Univ, Sch Geosci & Technol, Chengdu 610500, Peoples R China

Reprint 's Address:

  • [Han, Guilin]China Univ Geosci Beijing, State Key Lab Biogeol & Environm Geol, Beijing 100083, Peoples R China

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Source :

WATER RESEARCH

ISSN: 0043-1354

Year: 2024

Volume: 257

1 1 . 5 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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