Cu-catalyzed C-N bond cleavage of 3-Aminoindazoles for the C-H arylation of enamines - Details

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Zhou, Y. (Zhou, Y..) ^[1] | Wang, Y. (Wang, Y..) ^[2] | Song, Z. (Song, Z..) ^[3] | Nakano, T. (Nakano, T..) ^[4] | Song, Q. (Song, Q..) ^[5]

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Abstract：

The　Cu-catalyzed　C-H　arylation　of　enamines　via　the　oxidative　C-N　cleavage　of　3-Aminoindazoles　is　presented.　A　diverse　array　of　arylated　enamines　were　produced　in　decent　yields　with　a　wide　substrate　scope　under　mild　conditions.　Here,　3-Aminoindazoles　were　harnessed　as　novel　arylating　agents　via　a　radical　process.　©　2019　the　Partner　Organisations.

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[ 1 ] [Zhou, Y.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, College of Chemical Engineering at Huaqiao University, 668 Jimei Blvd, Xiamen, Fujian, 361021, China
[ 2 ] [Wang, Y.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, College of Chemical Engineering at Huaqiao University, 668 Jimei Blvd, Xiamen, Fujian, 361021, China
[ 3 ] [Song, Z.]Institute for Catalysis (ICAT), Hokkaido University, N 21 W 10, Kita-ku, Sapporo, 001-0021, Japan
[ 4 ] [Nakano, T.]Institute for Catalysis (ICAT), Hokkaido University, N 21 W 10, Kita-ku, Sapporo, 001-0021, Japan
[ 5 ] [Song, Q.]Institute of Next Generation Matter Transformation, College of Materials Science and Engineering, College of Chemical Engineering at Huaqiao University, 668 Jimei Blvd, Xiamen, Fujian, 361021, China
[ 6 ] [Song, Q.]Fujian University Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China

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Organic Chemistry Frontiers

ISSN： 2052-4110

Year： 2019

Issue： 1

Volume： 7

Page： 25-29

5 . 1 5 5

JCR@2019

4 . 6 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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